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- W1977819314 abstract "The reaction rate for the photochemical rearrangement of 1,6-N-(substituted-phenyl)aza-[60]fulleroid 1 to 1,2-N-(substituted-phenyl)aziridino-[60]fullerene 2 differed ca. 3000-fold depending on the position and number of methyl substituents on the N-phenyl group. The required time for the completion of the reaction decreased in the order 2,6-dimethylphenyl (1d) < 2-methylphenyl (1b) < phenyl (1a) < 4-methylphenyl (1c). The difference was mainly due to switching of the excited states between normal (fast reactions) and charge-separated (slow reactions) triplet states, which was induced by steric interactions between the N-phenyl group and the C60 moiety." @default.
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- W1977819314 date "2005-09-01" @default.
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- W1977819314 title "Drastic change in the rate of photochemical rearrangement of 1,6-(N-phenyl)aza-[60]fulleroids by switching the excited states through simple methyl substitution on the phenyl group" @default.
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- W1977819314 doi "https://doi.org/10.1016/j.tetlet.2005.07.133" @default.
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