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• W1977827170 abstract "Abstract The structures of fully and partially dehydrated zeolite Y Co2+ exchanged at pH 5.1, were determined by single-crystal synchrotron X-ray diffraction techniques in the cubic space group Fd 3 ¯ m and were refined to the final error indices R1/wR2 = 0.046/0.120 and 0.062/0.191, respectively. Two crystals were used; their unit-cell formulas are approximately |Co31Na8H5|[Si117Al75O384]-FAU and |Co30.5Na6(H3O)4(H2O)4H4|[Si117Al75O384]-FAU, respectively. In the fully dehydrated structure, Co2+ ions occupy sites I, I′ and II; the Na+ ions are also at site II. In the partially dehydrated structure, Co2+ occupies sites I′, II′, II, and III′; the Na+ ions are at site I′. Some H3O+ ions are seen in the partially dehydrated structure, and H+ ions must be present in both crystals for charge balance. Upon dehydration Co2+ ions move into the hexagonal prisms and Na+ ions move from sodalite cavities to supercages." @default.
• W1977827170 created "2016-06-24" @default.
• W1977827170 creator A5002772655 @default.
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• W1977827170 date "2013-04-01" @default.
• W1977827170 modified "2023-10-18" @default.
• W1977827170 title "Single-crystal structures of fully and partially dehydrated zeolite Y (FAU, Si/Al = 1.56) largely Co2+ exchanged at pH 5.1" @default.
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• W1977827170 doi "https://doi.org/10.1016/j.micromeso.2012.11.019" @default.
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