FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1977829341> ?p ?o ?g. }

• W1977829341 endingPage "3964" @default.
• W1977829341 startingPage "3964" @default.
• W1977829341 abstract "Three new rod-like dinuclear Ru(II) polypyridine compounds have been prepared and characterized and their absorption spectra, redox behaviour and photophysical properties have been investigated, by conventional steady-state absorption and luminescence spectroscopic methods and by time-resolved methods operating in the nanosecond and femtosecond time regimes. All the new species contain 1,4-bis(2,2′:6′,2″-terpyridin-4′-yl)benzene (4) as bridging ligand and 2,4-bis(2-pyridyl)-6-p-bromophenyl-1,3,5-triazine and/or 4′-(p-bromophenyl)-2,2′:6′,2″-terpyridine as peripheral ligands. In particular, 1 and 2 are symmetric dyads since the Ru(II) ions carry identical peripheral ligands (the triazine-based ligands in 1 and the terpyridine-based ligands in the case of 2), whereas 3 is a non-symmetric dyad since its two Ru(II) centers carry two different peripheral ligands (for the structural formulae of the compounds, see Chart 1). The absorption spectra and redox behaviour of the new compounds indicate, that each subunit of the dyads maintain its own peculiar properties in the dinuclear system, a requisite confirming the supramolecular nature of the systems. All the species exhibit metal-to-ligand charge-transfer (MLCT) emission, both at room temperature in fluid solution and at 77 K in rigid matrix. Luminescence lifetime and transient absorption spectroscopy reveal that efficient and fast photoinduced energy transfer takes place in the non-symmetric dyad 3 from the subunit containing the terpyridine peripheral ligand to the subunit containing the triazine-based peripheral ligand. However, given the complexity of the transient spectra and the overlapping timescales of the processes of the symmetric and non-symmetric systems, any detailed analysis of the ultrafast results aimed at the identification of specific intercomponent energy transfer steps, and therefore to kinetically characterize the directional energy transfer, appears to be speculative." @default.
• W1977829341 created "2016-06-24" @default.
• W1977829341 creator A5002792170 @default.
• W1977829341 creator A5003277818 @default.
• W1977829341 creator A5017012270 @default.
• W1977829341 creator A5045746735 @default.
• W1977829341 creator A5046874077 @default.
• W1977829341 creator A5051960473 @default.
• W1977829341 creator A5053942239 @default.
• W1977829341 creator A5066287991 @default.
• W1977829341 creator A5075611017 @default.
• W1977829341 creator A5078193467 @default.
• W1977829341 date "2009-01-01" @default.
• W1977829341 modified "2023-10-11" @default.
• W1977829341 title "Photoinduced energy transfer in a rod-like dinuclear Ru(ii) complex containing bis-pyridyl-1,3,5-triazine ligands" @default.
• W1977829341 cites W141356951 @default.
• W1977829341 cites W192653134 @default.
• W1977829341 cites W1964603841 @default.
• W1977829341 cites W1970393749 @default.
• W1977829341 cites W1984668192 @default.
• W1977829341 cites W1995712792 @default.
• W1977829341 cites W1997107645 @default.
• W1977829341 cites W2003123607 @default.
• W1977829341 cites W2004050537 @default.
• W1977829341 cites W2009542925 @default.
• W1977829341 cites W2017158424 @default.
• W1977829341 cites W2027580421 @default.
• W1977829341 cites W2034445094 @default.
• W1977829341 cites W2037636027 @default.
• W1977829341 cites W2042821724 @default.
• W1977829341 cites W2043775573 @default.
• W1977829341 cites W2045540077 @default.
• W1977829341 cites W2049745418 @default.
• W1977829341 cites W2052752040 @default.
• W1977829341 cites W2054422942 @default.
• W1977829341 cites W2056576629 @default.
• W1977829341 cites W2065497508 @default.
• W1977829341 cites W2069170355 @default.
• W1977829341 cites W2069506896 @default.
• W1977829341 cites W2076040523 @default.
• W1977829341 cites W2077959761 @default.
• W1977829341 cites W2081452949 @default.
• W1977829341 cites W2101990153 @default.
• W1977829341 cites W2151003442 @default.
• W1977829341 cites W2163751207 @default.
• W1977829341 cites W2312570034 @default.
• W1977829341 cites W2949485030 @default.
• W1977829341 doi "https://doi.org/10.1039/b820444f" @default.
• W1977829341 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19440595" @default.
• W1977829341 hasPublicationYear "2009" @default.
• W1977829341 type Work @default.
• W1977829341 sameAs 1977829341 @default.
• W1977829341 citedByCount "23" @default.
• W1977829341 countsByYear W19778293412012 @default.
• W1977829341 countsByYear W19778293412013 @default.
• W1977829341 countsByYear W19778293412014 @default.
• W1977829341 countsByYear W19778293412015 @default.
• W1977829341 countsByYear W19778293412016 @default.
• W1977829341 countsByYear W19778293412017 @default.
• W1977829341 countsByYear W19778293412019 @default.
• W1977829341 countsByYear W19778293412020 @default.
• W1977829341 countsByYear W19778293412022 @default.
• W1977829341 crossrefType "journal-article" @default.
• W1977829341 hasAuthorship W1977829341A5002792170 @default.
• W1977829341 hasAuthorship W1977829341A5003277818 @default.
• W1977829341 hasAuthorship W1977829341A5017012270 @default.
• W1977829341 hasAuthorship W1977829341A5045746735 @default.
• W1977829341 hasAuthorship W1977829341A5046874077 @default.
• W1977829341 hasAuthorship W1977829341A5051960473 @default.
• W1977829341 hasAuthorship W1977829341A5053942239 @default.
• W1977829341 hasAuthorship W1977829341A5066287991 @default.
• W1977829341 hasAuthorship W1977829341A5075611017 @default.
• W1977829341 hasAuthorship W1977829341A5078193467 @default.
• W1977829341 hasConcept C115624301 @default.
• W1977829341 hasConcept C116569031 @default.
• W1977829341 hasConcept C119824511 @default.
• W1977829341 hasConcept C121332964 @default.
• W1977829341 hasConcept C125287762 @default.
• W1977829341 hasConcept C148869448 @default.
• W1977829341 hasConcept C159985019 @default.
• W1977829341 hasConcept C170493617 @default.
• W1977829341 hasConcept C178790620 @default.
• W1977829341 hasConcept C185592680 @default.
• W1977829341 hasConcept C188027245 @default.
• W1977829341 hasConcept C192562407 @default.
• W1977829341 hasConcept C2776303721 @default.
• W1977829341 hasConcept C2781350956 @default.
• W1977829341 hasConcept C32891209 @default.
• W1977829341 hasConcept C49040817 @default.
• W1977829341 hasConcept C544153396 @default.
• W1977829341 hasConcept C55352516 @default.
• W1977829341 hasConcept C55493867 @default.
• W1977829341 hasConcept C62520636 @default.
• W1977829341 hasConcept C75473681 @default.
• W1977829341 hasConcept C8010536 @default.
• W1977829341 hasConcept C93275456 @default.
• W1977829341 hasConcept C95503338 @default.
• W1977829341 hasConceptScore W1977829341C115624301 @default.

• next