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• W1977901855 abstract "Novel hydrogen bonding diamide receptors viz., N , N I -bis(phenyl)iso phthalohydrazide ( I ) and N , N I -bis(2,4-dinitrophenyl)isophthalohydrazide ( II ), have been synthesized and characterized by IR, 1 H NMR and elemental analysis. Spectroscopic investigations indicate high affinity of these receptors for carbonate ion. Polyvinyl chloride (PVC) based membranes of ( I ) and ( II ) using tridodecylmethylammonium chloride (TDDMACl) as cation discriminator and diethylphthalate (DEP), dioctylphthalate (DOP), 1-chloronapthalene (CN), tris(2-ethylhexyl)phosphate (TEHP) and bis(2-ethylhexyl)sebacate (DOS) as plasticizing solvent mediators were prepared and investigated as CO 3 2− selective sensors. The best performance was shown by the membrane of composition (w/w) of ( II ) (4%):PVC (33%):CN (60%):TDDMACl (3%). This sensor works well over a wide concentration range 1.3 × 10 −7 to 1.0 × 10 −3 M with Nernstian compliance (29.0 mV decade −1 of activity) at pH 8.6 with a fast response time of ∼7 s and showed good selectivity for carbonate over a number of anions. The sensor exhibits adequate shelf life (two and half months) with good reproducibility (S.D. ± 0.3 mV) and could be used successfully for the determination of total inorganic carbon in water samples." @default.
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• W1977901855 date "2006-11-01" @default.
• W1977901855 modified "2023-09-24" @default.
• W1977901855 title "Anion recognition using newly synthesized hydrogen bonding diamide receptors: PVC based sensors for carbonate" @default.
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• W1977901855 doi "https://doi.org/10.1016/j.electacta.2006.06.037" @default.
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