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• W1977902665 abstract "Based on molecular theory, an equation of state (EOS) is derived for a mixture containing electrolytes in a mixed solvent. Calculations are performed for the ternary system watermethanollithium bromide. The equation of state follows from an expression for the Helmholtz energy; parameters are fitted to vapor-pressure, density, and osmotic-coefficient data between −10 and 120 °C from infinite dilution to 15 mol% salt. For the binary systems, deviations in vapor pressure are ∼ 2–4%. When applied to the ternary system, using only binary parameters, the EOS predicts vapor pressures with a mean deviation of 6% and vapor compositions with a mean deviation of < 1.5 mol%. The EOS presented here may be useful for calculating vaporliquid equilibria for electrolyte systems at high pressures." @default.
• W1977902665 created "2016-06-24" @default.
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• W1977902665 date "1987-01-01" @default.
• W1977902665 modified "2023-10-16" @default.
• W1977902665 title "Equation of state for solutions of electrolytes in mixed solvents" @default.
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• W1977902665 doi "https://doi.org/10.1016/0378-3812(87)90002-1" @default.
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