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- W1977982593 abstract "Abstract A simple, highly reproducible protocol for the hydrogenation of alkenes and alkynes and for the hydrogenolysis of O ‐benzyl ethers has been developed. The method features the in situ preparation of an active Pd 0 /C catalyst from Pd(OAc) 2 and charcoal, in methanol. The mild reaction conditions (25 °C) and low catalyst loading required (0.025 mol %), as well as the absence of contamination of the product by palladium residues (<4 ppb), make this a sustainable, useful process for organic chemists. Alternatively, the protocol can be carried out under microwave activation, to shorten the reaction times, with cyclohexene as the hydrogen source." @default.
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- W1977982593 date "2010-09-15" @default.
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- W1977982593 title "A Useful, Reliable and Safer Protocol for Hydrogenation and the Hydrogenolysis of <i>O</i> ‐Benzyl Groups: The In Situ Preparation of an Active Pd <sup>0</sup> /C Catalyst with Well‐Defined Properties" @default.
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- W1977982593 doi "https://doi.org/10.1002/chem.201001377" @default.
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