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- W1977983975 abstract "Synchrotron-radiation excited ion mass spectrometry has been used to study the 3s3${mathit{p}}^{6}$np(nensuremath{ge}4) resonances in argon at 25.0--29.3 eV. It is shown using a time-independent resonant scattering approach that the Fano parametrization may be applied to overlapping resonances. For the Dubau-Seaton profile an exact expression of the closed-channel phase shift is obtained. We find that regarding the window character of the Ar 3s series the Fano parameters calculated using the multichannel multiconfiguration Dirac-Fock method are in good agreement with those derived from fitting a convoluted Fano function to the measured n=4 autoionizing resonance. The Fano parameters are also derived from perfect fits to the 5ensuremath{le}nensuremath{le}8 resonances which tests the validity of this parametrization to overlapping members of an inner-valence electron resonance series. In contrast, a parametrization of the entire series based upon the Dubau-Seaton formula did not result in a good fit without modifications. Using the same value of the shape parameter we find, however, that the n=4 resonance can be accurately represented by both the Fano and Dubau-Seaton profiles." @default.
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- W1977983975 date "1994-08-01" @default.
- W1977983975 modified "2023-09-30" @default.
- W1977983975 title "Argon 3<i>s</i>autoionization resonances" @default.
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- W1977983975 doi "https://doi.org/10.1103/physreva.50.1218" @default.
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