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- W1977999476 abstract "We demonstrate the possibility of preparation of a mixed metal hexacyanoferrate system, silver-containing copper hexacyanoferrate, in the form of a thin film on glassy carbon electrode substrate. This novel microstructure is characterized using conventional cyclic voltammetry, visible absorption spectrophotometry, as well as solid-state electrochemistry in the absence of contact with liquid electrolyte. The results imply distinct physicochemical identity of the system in comparison to silver-free copper hexacyanoferrate. Incorporation of Ag influences the selectivity of counter-cation transport which supports redox reactions of the modified electrode in alkali metal supporting electrolytes. Thus the Ag-intercalated material may be considered for ion-exchange applications. Following in situ electroanalytical determinations, based on coulometry and stripping-like voltammetry, we postulate stoichiometries, AgICuIIFeIII(CN)6 and KAgICuIIFeIII(CN)6, for the oxidized and reduced structures." @default.
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- W1977999476 date "1996-02-01" @default.
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- W1977999476 title "Preparation and characterization of Ag-intercalated copper hexacyanoferrate films on electrodes" @default.
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- W1977999476 doi "https://doi.org/10.1002/elan.1140080203" @default.
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