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- W1978007228 abstract "The influence of 1,2-dipiperidinoethane (DPE) and tetraethylethylenediamine (TEEDA) on the butadienyl- and pentadienyllithium active centres has been examined by NMR and electronic spectroscopy. The effect of DPE on the butadienyllithium species differs from that of TEEDA in that the magnitudes of the 1H shifts are considerably smaller at any given [base]:[lithium] ratio. The trans conformation was found to be the preferred structure of the active centres in the presence of diamines. The electronic spectra of these dienyllithium active centres in the presence of these bases exhibited new peaks with γmax at 323–325 nm where the maximum influence of either base was seen at [base]:[lithium] ratios of ca two." @default.
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- W1978007228 date "1986-01-01" @default.
- W1978007228 modified "2023-09-27" @default.
- W1978007228 title "Spectroscopy of the complexation of polybutadienyl- and polypentadienyllithium by ditertiary bases—II. 1,2-Dipiperidinoethane and N,N,N′,N′-tetraethylethylenediamine" @default.
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- W1978007228 doi "https://doi.org/10.1016/0014-3057(86)90190-4" @default.
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