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- W1978013621 abstract "Abstract Pyridine-based macrocycles were prepared by treating 2,6-bis[[2′6′-bis(bromomethyl)-4′-methylphenoxy]methyl]pyridine 3 with the appropriate chiral aminoalcohols. The enantiomeric recognition of these macrocycles bearing aminoalcohol subunits of the pyridinocrown type ligand was evaluated for chiral organic ammonium salts by UV titration. The important differences were observed in the Ka values of (R)-Am2 and (S)-Am2 for (S,S,S)-1, (S,S,S)-2 and (S,S,S)-3 hosts, KS/KR = 5.0, KS/KR = 2.4 and KS/KR = 5.0, respectively. There seems to be a general tendency for hosts to recognise (S)-enantiomers for both Am1 and Am2." @default.
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- W1978013621 date "2009-07-01" @default.
- W1978013621 modified "2023-10-18" @default.
- W1978013621 title "The enantiomeric recognition of chiral organic ammonium salts by chiral pyridino-macrocycles bearing aminoalcohol subunits" @default.
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- W1978013621 doi "https://doi.org/10.1016/j.tetasy.2009.06.010" @default.
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