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• W1978016783 abstract "The crystal structure of meso-commo-[3,3′-Fe{4-(Me2S)-1,2-C2B9H10}2], meso-1, has been determined. The molecules of the complex pack to form layers coincident with the [−1 0 1] planes. Both intra- and inter-molecular BHδ− ⋯Sδ+ electrostatic interactions occur in the crystal, with H ⋯ S distances of 2.62 and 2.94 Å, respectively. These interactions can be regarded as involving reversed-polarity hydrogen bonds. The intermolecular interactions form a two-dimensional network within each of the molecular layers. The solid-state Raman spectrum of meso-1 is clearly distinguishable from that of its DD/LL-isomers. The p-toluenesulfonate and bisulfate salts of the DD/LL-commo-[3,3′-Fe{4-(Me2S)-1,2-C2B9H10}2]+ cation have been synthesised in good yield by the oxidation of DD/LL-commo-[3,3′-Fe{4-(Me2S)-1,2-C2B9H10}2] with p-benzoquinone." @default.
• W1978016783 created "2016-06-24" @default.
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• W1978016783 date "1995-08-01" @default.
• W1978016783 modified "2023-10-11" @default.
• W1978016783 title "Diastereomers of the carborane sandwich complex commo-[3,3-Fe{4-(Me2S)-1,2-C2B9H10}2]; crystal structure of meso-[Fe(C2B9H10SMe2)2]" @default.
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• W1978016783 doi "https://doi.org/10.1016/0022-328x(95)05533-u" @default.
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