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- W1978021236 abstract "Group 6 hexacarbonyls were supported on aluminas pretreated at three different temperatures. The degree of dehydroxylation was found to affect the temperature-programmed decomposition (TPDE) profile of Mo(CO)6 more than those of Cr(CO)6 and W(CO)6. Different reducible chromium surface species on alumina 500 were suggested: Two reduction maxima appeared when the sample was heated to 200°C and oxidised with pulse chemisorption of oxygen prior to reduction. After heating to 500°C only one broad reduction maximum appeared. Partially oxidised molybdenum on alumina 500 gave a temperature-programmed reduction (TPR) maximum at about 365°C, independent of the decarbonylation conditions. Successive reduction–oxidation cycles showed the irreversibility of partially oxidised molybdenum." @default.
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- W1978021236 date "1984-06-01" @default.
- W1978021236 modified "2023-09-23" @default.
- W1978021236 title "Fischer-Tropsch synthesis over supported molybdenum hexacarbonyl" @default.
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- W1978021236 doi "https://doi.org/10.1016/0021-9517(84)90211-2" @default.
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