FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1978022996> ?p ?o ?g. }

• W1978022996 endingPage "1442" @default.
• W1978022996 startingPage "1425" @default.
• W1978022996 abstract "A microscopic theory of the structure of compressible associating AB regular heteropolymer fluids is proposed based on polymer integral equation methods. The theory is employed to systematically explore, as a function of temperature, the influence of sticky group attractive energy, concentration, degree of blockiness, and global architecture (telechelic, surfactant, multiblock) on self-assembly and microdomain formation as encoded in small-angle partial scattering structure factors. Characteristic apparent spinodal and order−disorder temperatures are estimated, and strong composition fluctuation effects are always present. The evolution of collective properties derived from scattering profiles such as microdomain period, intermultiplet coherence length, degree of Porodlike scattering, and modification of wide-angle intensity, with polymer structure and thermodynamic state are established. At fixed bare (chemical) driving force, end-functionalized architectures are found to form more ordered microphase-separated fluids than the multiblock analogues. Increasing sequence length also enhances self-assembly even at fixed global sticky group composition. Significant differences between telechelics composed of unimer sticky groups vs mini-triblocks are found, with the former displaying many self-assembly features not in accord with classic block copolymer behavior. Semiquantitative comparisons with small-angle X-ray scattering experiments suggest the theory provides a realistic description of self-assembly in ionomer melts, and failure of incompressible random phase approximation approaches for many properties is documented. Predictions for the majority (nonpolar) monomer density fluctuations, and cross-correlations, are obtained. Subtle, but systematic structural changes are induced by the minority group self-assembly process which may be amenable to direct measurement using small-angle neutron scattering and are possibly of mechanical property relevance." @default.
• W1978022996 created "2016-06-24" @default.
• W1978022996 creator A5045572539 @default.
• W1978022996 creator A5070437312 @default.
• W1978022996 date "2000-01-27" @default.
• W1978022996 modified "2023-09-23" @default.
• W1978022996 title "Microdomain Scale Organization and Scattering Patterns of Associating Polymer Melts" @default.
• W1978022996 cites W1967416836 @default.
• W1978022996 cites W1967728492 @default.
• W1978022996 cites W1975251014 @default.
• W1978022996 cites W1976572376 @default.
• W1978022996 cites W1979470495 @default.
• W1978022996 cites W1981575070 @default.
• W1978022996 cites W1988320685 @default.
• W1978022996 cites W1991347946 @default.
• W1978022996 cites W2001383166 @default.
• W1978022996 cites W2002766838 @default.
• W1978022996 cites W2006298655 @default.
• W1978022996 cites W2007751185 @default.
• W1978022996 cites W2008928884 @default.
• W1978022996 cites W2014559082 @default.
• W1978022996 cites W2019766682 @default.
• W1978022996 cites W2020627046 @default.
• W1978022996 cites W2022412916 @default.
• W1978022996 cites W2027510179 @default.
• W1978022996 cites W2028297568 @default.
• W1978022996 cites W2031452616 @default.
• W1978022996 cites W2034357253 @default.
• W1978022996 cites W2034501059 @default.
• W1978022996 cites W2035705405 @default.
• W1978022996 cites W2040614146 @default.
• W1978022996 cites W2046962828 @default.
• W1978022996 cites W2050945279 @default.
• W1978022996 cites W2052265476 @default.
• W1978022996 cites W2052566422 @default.
• W1978022996 cites W2058827055 @default.
• W1978022996 cites W2059559865 @default.
• W1978022996 cites W2064428962 @default.
• W1978022996 cites W2070246996 @default.
• W1978022996 cites W2077537974 @default.
• W1978022996 cites W2080362361 @default.
• W1978022996 cites W2088490755 @default.
• W1978022996 cites W2088518873 @default.
• W1978022996 cites W2091348876 @default.
• W1978022996 cites W2092807836 @default.
• W1978022996 cites W2124787352 @default.
• W1978022996 cites W2172949807 @default.
• W1978022996 doi "https://doi.org/10.1021/ma9912913" @default.
• W1978022996 hasPublicationYear "2000" @default.
• W1978022996 type Work @default.
• W1978022996 sameAs 1978022996 @default.
• W1978022996 citedByCount "24" @default.
• W1978022996 countsByYear W19780229962014 @default.
• W1978022996 countsByYear W19780229962015 @default.
• W1978022996 countsByYear W19780229962016 @default.
• W1978022996 countsByYear W19780229962018 @default.
• W1978022996 countsByYear W19780229962020 @default.
• W1978022996 countsByYear W19780229962021 @default.
• W1978022996 countsByYear W19780229962023 @default.
• W1978022996 crossrefType "journal-article" @default.
• W1978022996 hasAuthorship W1978022996A5045572539 @default.
• W1978022996 hasAuthorship W1978022996A5070437312 @default.
• W1978022996 hasConcept C104015590 @default.
• W1978022996 hasConcept C11135259 @default.
• W1978022996 hasConcept C112416005 @default.
• W1978022996 hasConcept C120665830 @default.
• W1978022996 hasConcept C121332964 @default.
• W1978022996 hasConcept C131888329 @default.
• W1978022996 hasConcept C132841051 @default.
• W1978022996 hasConcept C134088382 @default.
• W1978022996 hasConcept C159467904 @default.
• W1978022996 hasConcept C159985019 @default.
• W1978022996 hasConcept C178790620 @default.
• W1978022996 hasConcept C185592680 @default.
• W1978022996 hasConcept C191486275 @default.
• W1978022996 hasConcept C192562407 @default.
• W1978022996 hasConcept C26065003 @default.
• W1978022996 hasConcept C29234059 @default.
• W1978022996 hasConcept C41625074 @default.
• W1978022996 hasConcept C44280652 @default.
• W1978022996 hasConcept C521977710 @default.
• W1978022996 hasConcept C55493867 @default.
• W1978022996 hasConcept C57879066 @default.
• W1978022996 hasConcept C8010536 @default.
• W1978022996 hasConcept C85272257 @default.
• W1978022996 hasConcept C97355855 @default.
• W1978022996 hasConceptScore W1978022996C104015590 @default.
• W1978022996 hasConceptScore W1978022996C11135259 @default.
• W1978022996 hasConceptScore W1978022996C112416005 @default.
• W1978022996 hasConceptScore W1978022996C120665830 @default.
• W1978022996 hasConceptScore W1978022996C121332964 @default.
• W1978022996 hasConceptScore W1978022996C131888329 @default.
• W1978022996 hasConceptScore W1978022996C132841051 @default.
• W1978022996 hasConceptScore W1978022996C134088382 @default.
• W1978022996 hasConceptScore W1978022996C159467904 @default.
• W1978022996 hasConceptScore W1978022996C159985019 @default.
• W1978022996 hasConceptScore W1978022996C178790620 @default.
• W1978022996 hasConceptScore W1978022996C185592680 @default.

• next