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- W1978026024 abstract "Experimental and computational studies suggest that 375 nm excitation of arylchlorodiazirines furnishes their S1 excited states with lengthened C−N bonds, a positive charge at the para and diazirine carbon atoms, and a negative charge at the nitrogen atoms. These structures rationalize the observed solvent and substituent effects on the excited state lifetimes." @default.
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- W1978026024 date "2009-11-02" @default.
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- W1978026024 title "Ultrafast Spectroscopy of Arylchlorodiazirines: Hammett Correlations of Excited State Lifetimes" @default.
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- W1978026024 doi "https://doi.org/10.1021/ja907915z" @default.
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