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- W1978029078 abstract "Three materials were studied by laser ablation/Fourier transform mass spectrometry, using 266 nm laser radiation: a copolymer of ethylene and tetrafluoroethylene (ETFE), polyphenylene sulfide (PPS), and a diamond-like carbon film (DLC). In each case, positive ion mass spectra exhibit primarily even-numbered, high mass carbon clusters (‘‘fullerenes’’) of the type previously reported for graphite ablation. In the case of ETFE, a large C+60 peak (‘‘buckminsterfullerene’’) was observed. The polymer spectra showed a strong dependence on the number of laser pulses on one spot and the laser power density. For ETFE, the fullerene ion relative intensity first increases and then decreases as a function of the number of laser pulses. For the DLC film, fullerenes are observed with a single laser pulse on a fresh spot of the sample. The results are interpreted in terms of a gas phase growth model for the fullerene ion formation." @default.
- W1978029078 created "2016-06-24" @default.
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- W1978029078 date "1990-02-15" @default.
- W1978029078 modified "2023-09-23" @default.
- W1978029078 title "Formation of high mass carbon cluster ions from laser ablation of polymers and thin carbon films" @default.
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- W1978029078 doi "https://doi.org/10.1063/1.458019" @default.
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