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• W1978030030 endingPage "88" @default.
• W1978030030 startingPage "85" @default.
• W1978030030 abstract "A series of unsaturated ferrocene derivatives with the formula FcCHCHX (XCHO, CN, COCH3, COOCH3, 4-py; Fc, ferrocene) were synthesized. They were found to exhibit reversible one-electron oxidation and two one-electron reduction steps. Quenching of the excited state of Ru(bpy)32+ (bpy, 2,2′-bipyridine) by the ferrocene derivatives was also studied. Quenching occurs mainly via electron transfer on the ferrocenyl group in acetonitrile. The results are confirmed by molecular orbital calculations using the CNDO method. A quenching mechanism is suggested. The bimolecular quenching rate constants were obtained from the Stern-Volmer equation. Linear relationships are obtained for a plot of log Kq vs. −ΔG of electron transfer." @default.
• W1978030030 created "2016-06-24" @default.
• W1978030030 creator A5044461492 @default.
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• W1978030030 date "1995-02-01" @default.
• W1978030030 modified "2023-09-26" @default.
• W1978030030 title "Quenching by unsaturated ferrocene derivatives of the luminescence if Ru(bpy)32+" @default.
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• W1978030030 doi "https://doi.org/10.1016/1010-6030(94)03934-m" @default.
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