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• W1978049668 endingPage "2255" @default.
• W1978049668 startingPage "2248" @default.
• W1978049668 abstract "Inorganic nanotubes (INT) were used for the first time to prepare advanced polymer nanocomposites by means of the most simple, cost-effective and ecologically friendly way (i.e., melt-processing route). The polymer matrix was isotactic polypropylene (iPP) and the inorganic fillers were molybdenum disulfide nanotubes (MoS(2)). The effect of INT-MoS(2) concentration and the crystallization temperature on the isothermal crystallization behavior of iPP was investigated using differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXS). It has been observed that INT-MoS(2) affects the crystallization of nanocomposites remarkably, which can be attributed to the nucleating effect of INT-MoS(2) on the monoclinic α-crystal form of iPP. Other parameters such as the Avrami exponent and the fold surface free energy of crystallization of iPP chains in the nanocomposites were obtained in order to determine the effect of the INT-MoS(2) on them. The addition of INT-MoS(2) remarkably influences the kinetics of nucleation and growth of iPP with a decrease in the fold surface free energy of 11-24%." @default.
• W1978049668 created "2016-06-24" @default.
• W1978049668 creator A5041171932 @default.
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• W1978049668 date "2011-02-22" @default.
• W1978049668 modified "2023-10-03" @default.
• W1978049668 title "Isothermal Crystallization Kinetics of Novel Isotactic Polypropylene/MoS₂ Inorganic Nanotube Nanocomposites" @default.
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• W1978049668 doi "https://doi.org/10.1021/jp111965b" @default.
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