Matches in SemOpenAlex for { <https://semopenalex.org/work/W1978068611> ?p ?o ?g. }
- W1978068611 abstract "High-resolution studies of the host-guest inclusion compound n-hexadecane/urea are reported at atmospheric pressure, using both cold neutrons and x-ray diffraction. This intergrowth crystal presents a misfit parameter, defined by the ratio c(h)/c(g) (c(host)/c(guest)), which is temperature independent and irrational (γ = 0.486 ± 0.002) from 300 to 30 K. Three different structural phases are reported for this aperiodic crystal over this temperature range. The crystallographic superspaces are of rank 4 in phases I and II, whereas phase III is associated with an increase in rank to 5, with a supplementary misfit parameter (δ = 0.058 ± 0.002) that is constant throughout this phase. The superspace group of phase I is hexagonal P6(1)22(00γ) down to T(c1) = 149.5 ± 0.5 K; phase II, which persists down to T(c2) = 127.8 ± 0.5 K is orthorhombic P2(1)2(1)2(1)(00γ), and phase III is orthorhombic P2(1)2(1)2(1)(00γ)(00δ)." @default.
- W1978068611 created "2016-06-24" @default.
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- W1978068611 date "2011-11-28" @default.
- W1978068611 modified "2023-10-18" @default.
- W1978068611 title "Confined linear molecules inside an aperiodic supramolecular crystal: The sequence of superspace phases in <i>n-</i>hexadecane/urea" @default.
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- W1978068611 doi "https://doi.org/10.1063/1.3663711" @default.
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