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- W1978084195 abstract "The parallel (A1) and perpendicular (E) bands of the CH bending overtone, 2ν4, of CHF3 have been recorded at Doppler-limited resolution at room temperature using a difference-frequency laser spectrometer. The l = 0 component, 2ν40(A1), and the l = +2 component, 2ν4+2(E) (accessed by ΔK = −1 transitions), are only weakly perturbed by a mutual l-type resonance near the K′ = 31 and 33 levels, respectively; they can be fit to ≤0.0002 cm−1, approaching the experimental precision. The 2ν4−2(E) component (accessed by ΔK = +1 transitions) is strongly perturbed, principally by anharmonic and Coriolis resonances with 2ν3 + ν4±1(E). This perturbing state, though not observed directly, can be well specified by its influence on 2ν4−2. Additional localized resonances, arising from a multitude of possible combinations of lower frequency vibrations, are alos observed in the high K levels of 2ν4−2. These increase the rms deviation of the fit to the ΔK = +1 transitions, but a reliable set of deperturbed constants can be obtained by judicious selection of the data." @default.
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- W1978084195 date "1988-08-01" @default.
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- W1978084195 title "Doppler-limited spectra of the CH bending overtone of fluoroform" @default.
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- W1978084195 doi "https://doi.org/10.1016/0022-2852(88)90090-2" @default.
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