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• W1978090849 abstract "Abstract Four new isostructural rare earth manganese stannides, namely RE3MnSn5−x (x=0.16(6), 0.29(1) for RE=Tm, x=0.05(8), 0.21(3) for RE=Lu), have been obtained by reacting the mixture of corresponding pure elements at high temperature. Single-crystal X-ray diffraction studies revealed that they crystallized in the orthorhombic space group Pnma (No. 62) with cell parameters of a=18.384(9)–18.495(6) A, b=6.003(3)–6.062(2) A, c=14.898(8)–14.976(4) A, V=1644.3(14)–1679.0(9) A3 and Z=8. Their structures belong to the Hf3Cr2Si4 type and feature a 3D framework composed of 1D [Mn2Sn7] chains interconnected by [Sn3] double chains via Sn–Sn bonds, forming 1D large channels based on [Mn4Sn16] 20-membered rings along the b-axis, which are occupied by the rare earth atoms. Electronic structure calculations based on density functional theory (DFT) for idealized “RE3MnSn5” model indicate that these compounds are metallic, which are in accordance with the results from temperature-dependent resistivity measurements." @default.
• W1978090849 created "2016-06-24" @default.
• W1978090849 creator A5003824926 @default.
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• W1978090849 date "2010-09-01" @default.
• W1978090849 modified "2023-09-25" @default.
• W1978090849 title "Syntheses and crystal structures of RE3MnSn5−x (RE=Tm, Lu) with 3D Mn–Sn framework" @default.
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• W1978090849 doi "https://doi.org/10.1016/j.jssc.2010.07.003" @default.
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