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- W1978098759 abstract "The reaction of a transition-metal hydride with an unsaturated substrate is a critical step in several catalytic reactions. Commonly accepted mechanisms for homogeneous hydrogenation and hydroformylation have traditionally involved even-electron intermediates conforming to the 16- and 18-electron rule. Recently, kinetic and spectroscopic (CIDNP) evidence has been reported in support of odd-electron pathways for reactions of metal hydrides with substituted styrenes, anthracenes, allenes, and conjugated dienes, all of which form stabilized (benzylic or allylic) radicals. The authors report a new approach, in which metal hydrides are reacted with vinylcyclopropanes, which contain a radical clock." @default.
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- W1978098759 date "1987-10-01" @default.
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- W1978098759 title "Hydrogen atom transfer reactions of transition-metal hydrides. Utilization of a radical rearrangement in the determination of hydrogen atom transfer rates" @default.
- W1978098759 doi "https://doi.org/10.1021/ja00255a067" @default.
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