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- W1978102523 abstract "FTIR measurements were carried out on matrix-isolated calcium dihalide vapours. CaF2, CaCl2, CaBr2 and CaI2 samples were vaporized at temperatures ranging from 1100 K to 1700 K and the vapours were trapped in argon and krypton matrices. Bands of monomers, dimers and in one case of a more complex aggregate were observed. The spectra were interpreted on the basis of polarizable ion model calculations. Regarding the structure of the dimer molecule, D2h symmetry was established from the experimental measurements and theoretical results. A trimer molecule was found for CaF2 and a D2d symmetry structure is suggested for it." @default.
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- W1978102523 date "1989-01-01" @default.
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- W1978102523 title "FTIR matrix isolation study on gaseous calcium dihalide molecules" @default.
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