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- W1978132556 abstract "Abstract The acid NaPO 3 has been potentiometrically titrated with the carbonates of Li, Na, K, Ca, Sr and Ba in molten KNO 3 at 350°C. Both “forward” and “backward“ titration curves show marked potential inflexions at simple acid: oxide-ion donor ratios. The reaction products depend on the cation of the titrant, and in some cases on the route of the reaction. The P:O and P:e ratios of the compounds formed at the disappearance of PO 3 − (in forward experiments) or CO 3 2− (in backward ones) are proposed to characterize the acid character of the cations. Acidity decreases in the succession Ca > Li > Sr > Ba > Na, K." @default.
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- W1978132556 date "1968-03-01" @default.
- W1978132556 modified "2023-10-14" @default.
- W1978132556 title "Potentiometric acid-base titrations in molten salts—V. A comparative study on the acid character of some of group 1 and group 2 cations" @default.
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- W1978132556 doi "https://doi.org/10.1016/0013-4686(68)87012-4" @default.
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