FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1978138321> ?p ?o ?g. }

• W1978138321 endingPage "1309" @default.
• W1978138321 startingPage "1300" @default.
• W1978138321 abstract "Zerovalent group VI metal chemistry of anionic bis((diphenylphosphino)methyl)diphenylborate (Ph2BP2) offers some surprises in comparison to the chemistry of analogous complexes of neutral bidentate phosphines. The enhanced donor ability of Ph2BP2 relative to related bis-PPh2 ligands is confirmed by IR spectral analysis of [ASN][M(CO)4(Ph2BP2)] (ASN = 5-azoniaspiro[4.4]nonane; M = Cr, Mo, W). The mononitriles [ASN][fac-M(CO)3(RCN)(Ph2BP2)] (M = Cr, R = Me; M = Mo, R = Et; M = W, R = Et) are useful reagents for the introduction of sulfur dioxide and isocyanides to the π-basic M(CO)3(Ph2BP2) fragment. While the fundamental coordination chemistry of this anionic fragment mostly mirrors that of its conventional neutral cousins, the electronic impact of Ph2BP2 leads to divergent reactivity in some cases. For example, the sulfur dioxide complexes [ASN][mer-M(CO)3(SO2)(Ph2BP2)] (M = Mo, W) are unreactive toward CH2N2, dramatically different from the case for mer-M(CO)3(SO2)(L2) (L2 = dppm, dppe, dppp). The spectral data of [ASN][Mo(CO)3(CNC6H4(2-NH2))(Ph2BP2)] and [ASN][Mo(CO)3(CNCH2CH2NH2)(Ph2BP2)], salts containing the first anions of 2-aminophenyl isocyanide and 2-aminoethyl isocyanide, respectively, indicate that the anionic M(CO)3(Ph2BP2) fragment may be more useful than neutral M(CO)3(dppe) for the π-back-bonding induced stabilization of ligands prepared via template syntheses." @default.
• W1978138321 created "2016-06-24" @default.
• W1978138321 creator A5024798285 @default.
• W1978138321 creator A5064813076 @default.
• W1978138321 creator A5066277841 @default.
• W1978138321 creator A5067680489 @default.
• W1978138321 creator A5081148258 @default.
• W1978138321 creator A5087590232 @default.
• W1978138321 date "2014-02-24" @default.
• W1978138321 modified "2023-09-23" @default.
• W1978138321 title "Group VI Metal Carbonyl Complexes of Bis((diphenylphosphino)methyl)diphenylborate and an Assessment of Their Utility for Template Ligand Syntheses" @default.
• W1978138321 cites W1644830399 @default.
• W1978138321 cites W1971733222 @default.
• W1978138321 cites W1973279047 @default.
• W1978138321 cites W1973385871 @default.
• W1978138321 cites W1981332869 @default.
• W1978138321 cites W1981856550 @default.
• W1978138321 cites W1982037467 @default.
• W1978138321 cites W1983809335 @default.
• W1978138321 cites W1984627523 @default.
• W1978138321 cites W1985189821 @default.
• W1978138321 cites W1991008977 @default.
• W1978138321 cites W1996023141 @default.
• W1978138321 cites W2006477698 @default.
• W1978138321 cites W2010378133 @default.
• W1978138321 cites W2023612975 @default.
• W1978138321 cites W2024044771 @default.
• W1978138321 cites W2026196171 @default.
• W1978138321 cites W2027870891 @default.
• W1978138321 cites W2028709413 @default.
• W1978138321 cites W2034070354 @default.
• W1978138321 cites W2039564907 @default.
• W1978138321 cites W2043996384 @default.
• W1978138321 cites W2048387594 @default.
• W1978138321 cites W2052133158 @default.
• W1978138321 cites W2056105588 @default.
• W1978138321 cites W2063728298 @default.
• W1978138321 cites W2075857751 @default.
• W1978138321 cites W2082899817 @default.
• W1978138321 cites W2089151356 @default.
• W1978138321 cites W2091328090 @default.
• W1978138321 cites W2101758019 @default.
• W1978138321 cites W2138097468 @default.
• W1978138321 cites W2141333255 @default.
• W1978138321 cites W2146773381 @default.
• W1978138321 cites W2151256381 @default.
• W1978138321 cites W2153891819 @default.
• W1978138321 cites W2324869301 @default.
• W1978138321 cites W2328207689 @default.
• W1978138321 cites W2329318094 @default.
• W1978138321 doi "https://doi.org/10.1021/om5001056" @default.
• W1978138321 hasPublicationYear "2014" @default.
• W1978138321 type Work @default.
• W1978138321 sameAs 1978138321 @default.
• W1978138321 citedByCount "3" @default.
• W1978138321 countsByYear W19781383212015 @default.
• W1978138321 countsByYear W19781383212022 @default.
• W1978138321 crossrefType "journal-article" @default.
• W1978138321 hasAuthorship W1978138321A5024798285 @default.
• W1978138321 hasAuthorship W1978138321A5064813076 @default.
• W1978138321 hasAuthorship W1978138321A5066277841 @default.
• W1978138321 hasAuthorship W1978138321A5067680489 @default.
• W1978138321 hasAuthorship W1978138321A5081148258 @default.
• W1978138321 hasAuthorship W1978138321A5087590232 @default.
• W1978138321 hasConcept C116569031 @default.
• W1978138321 hasConcept C142724271 @default.
• W1978138321 hasConcept C155647269 @default.
• W1978138321 hasConcept C165176872 @default.
• W1978138321 hasConcept C170493617 @default.
• W1978138321 hasConcept C178516000 @default.
• W1978138321 hasConcept C178790620 @default.
• W1978138321 hasConcept C185592680 @default.
• W1978138321 hasConcept C204787440 @default.
• W1978138321 hasConcept C2776910235 @default.
• W1978138321 hasConcept C2777010268 @default.
• W1978138321 hasConcept C40875361 @default.
• W1978138321 hasConcept C544153396 @default.
• W1978138321 hasConcept C55493867 @default.
• W1978138321 hasConcept C68913812 @default.
• W1978138321 hasConcept C71240020 @default.
• W1978138321 hasConcept C71924100 @default.
• W1978138321 hasConceptScore W1978138321C116569031 @default.
• W1978138321 hasConceptScore W1978138321C142724271 @default.
• W1978138321 hasConceptScore W1978138321C155647269 @default.
• W1978138321 hasConceptScore W1978138321C165176872 @default.
• W1978138321 hasConceptScore W1978138321C170493617 @default.
• W1978138321 hasConceptScore W1978138321C178516000 @default.
• W1978138321 hasConceptScore W1978138321C178790620 @default.
• W1978138321 hasConceptScore W1978138321C185592680 @default.
• W1978138321 hasConceptScore W1978138321C204787440 @default.
• W1978138321 hasConceptScore W1978138321C2776910235 @default.
• W1978138321 hasConceptScore W1978138321C2777010268 @default.
• W1978138321 hasConceptScore W1978138321C40875361 @default.
• W1978138321 hasConceptScore W1978138321C544153396 @default.
• W1978138321 hasConceptScore W1978138321C55493867 @default.
• W1978138321 hasConceptScore W1978138321C68913812 @default.
• W1978138321 hasConceptScore W1978138321C71240020 @default.
• W1978138321 hasConceptScore W1978138321C71924100 @default.

• next