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- W1978151840 abstract "Abstract A comparative study of electrical properties of two systems of glasses x LiF (100 − x )BaNbOF 5 and x LiF (100 − x ) (0.3AlF 3 · 0.7BaNbOF 5 ) ( x = 10−60 mol%) has been carried out as a function of LiF content. A minimum in ionic conductivity and a maximum in activation energy has been detected in both systems. It was found that, in the LiF-BaNbOF 5 binary system, the maximal activation energy and the minimal ionic conductivity occur at different LiF concentrations. By analogy with many ZrF 4 -based fluoride glasses and the comparison of the influence of AlF 3 on the transport properties of the glasses with low and high LiF content, it is proposed that for the ternary system the transport properties mainly result from the contribution of mobile F − ions in the low LiF content ( ⩽ 25 mol%) region. In the high LiF concentration ( > 25 mol%) domain, the ionic conductivity is mainly governed by the migration of Li + ions. For binary systems, in the low LiF content ( ⩽ 25 mol%) region, the transport properties mainly result from the F − ions; in the range of LiF concentration between 25 and 50 mol%, both Li + and F − ions are responsible for the conduction; when the LiF concentration is higher than 50 mol%, the ionic conductivity of the glasses is mainly dominated by the migration of Li + ions." @default.
- W1978151840 created "2016-06-24" @default.
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- W1978151840 date "1992-01-01" @default.
- W1978151840 modified "2023-09-24" @default.
- W1978151840 title "Electrical conductivity of LiFAlF3BaNbOF5 quasi-fluoride glasses" @default.
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- W1978151840 doi "https://doi.org/10.1016/s0022-3093(05)80774-4" @default.
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