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- W1978169785 abstract "Abstract Three Cd(II) or Co(II) macroacyclic Schiff-base complexes [CoL1Br]ClO4 (1), [CdL2Cl]ClO4 (2) and [CdL3(NO3)]ClO4 (3) were prepared by template condensation of 2-pyridinecarboxaldehyde and three different amines containing piperazine moiety, N,N′-bis(2-aminoethyl)piperazine, N,N′(2-aminoethyl)(3-aminopropyl)piperazine and N,N′-bis(3-aminopropyl)piperazine, in the presence of Co(II) or Cd(II) metal ions, respectively. All complexes have been studied with IR, FAB mass and microanalysis and for complex (3) by 1H and 13C NMR spectra. One of these complexes, [CdL3(NO3)]ClO4 (3) has been characterized through X-ray crystallography. In complex (3), the Cd(II) ion is coordinated by the six nitrogen donor atoms from the ligand and by one oxygen atom from a monodentate nitrate ion in a N6O environment." @default.
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- W1978169785 date "2009-11-01" @default.
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- W1978169785 title "Synthesis and characterization of some new Co(II) and Cd(II) macroacyclic Schiff-base complexes containing piperazine moiety" @default.
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- W1978169785 doi "https://doi.org/10.1016/j.poly.2009.08.021" @default.
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