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• W1978175096 abstract "Results of theoretical and experimental studies of 3d states of divalent Fe ions in Fe[C{sub 2}H{sub 5}PO{sub 3}]H{sub 2}O are reported. Partial density of the Fe3d states is calculated in the LDA+U formalism and used for modeling the final state of emission in FeL{sub 2,3} x-ray spectra obtained at near-threshold excitation. The variation of the spectral shape with the energy of incident radiation is discussed. For the excitation energy near the FeL{sub 2} threshold, an anomalous enhancement of L{sub 2} emission is observed. This effect is interpreted as a result of resonance interaction between two radiation channels. The first of them is a normal fluorescence, which is static in the energy scale of photons and which is due to ionization of Fe atoms. The other channel is a ''drifting'' emission due to excitation of Fe atoms in the course of absorption of incident radiation." @default.
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• W1978175096 date "2001-01-31" @default.
• W1978175096 modified "2023-09-28" @default.
• W1978175096 title "Inelastic x-ray scattering measurements of iron organophosphonate" @default.
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• W1978175096 doi "https://doi.org/10.1103/physrevb.63.075113" @default.
• W1978175096 hasPublicationYear "2001" @default.
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