Matches in SemOpenAlex for { <https://semopenalex.org/work/W1978177588> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W1978177588 endingPage "6095" @default.
- W1978177588 startingPage "6090" @default.
- W1978177588 abstract "Rotational relaxation of two structurally similar nondipolar solutes, 2,5-dimethyl-1,4-dioxo-3,6-diphenylpyrrolo[3,4-c]pyrrole (DMDPP) and 1,4-dioxo-3,6-diphenylpyrrolo[3,4-c]pyrrole (DPP), has been examined in four isomeric butanols as a function of temperature in order to find out how the rotation of the solute molecules is influenced by the solute−solvent interaction strength. It has been observed that the hydrogen bonding interactions with the butanols do not influence the rotation of DMDPP. On the other hand, the rotation of DPP is affected by its interactions with the solvents, and as a result the reorientation times of DPP have been found to be over a factor of 2 longer than that of DMDPP. Two sets of reorientation times have been obtained, one corresponding to DMDPP and the other to DPP, when the reorientation times of both probes were normalized by the solvent viscosities. The observed pattern is a consequence of almost identical interaction strengths between the four isomeric butanols and the given probes. These results indicate that the relative differences in the hydrogen bond donating abilities of the butanols do not manifest in the measured reorientation times of the solute molecules." @default.
- W1978177588 created "2016-06-24" @default.
- W1978177588 creator A5016349284 @default.
- W1978177588 creator A5041404847 @default.
- W1978177588 date "2004-06-25" @default.
- W1978177588 modified "2023-10-11" @default.
- W1978177588 title "Rotational Dynamics of Nondipolar Probes in Butanols: Correlation of Reorientation Times with Solute−Solvent Interaction Strengths" @default.
- W1978177588 cites W1965138470 @default.
- W1978177588 cites W1967476537 @default.
- W1978177588 cites W1979133188 @default.
- W1978177588 cites W1983279743 @default.
- W1978177588 cites W1995029473 @default.
- W1978177588 cites W1999340625 @default.
- W1978177588 cites W2009085406 @default.
- W1978177588 cites W2010182745 @default.
- W1978177588 cites W2013554130 @default.
- W1978177588 cites W2016634429 @default.
- W1978177588 cites W2016998980 @default.
- W1978177588 cites W2020293018 @default.
- W1978177588 cites W2022950330 @default.
- W1978177588 cites W2027547439 @default.
- W1978177588 cites W2035353203 @default.
- W1978177588 cites W2040253842 @default.
- W1978177588 cites W2049175995 @default.
- W1978177588 cites W2052204880 @default.
- W1978177588 cites W2053973586 @default.
- W1978177588 cites W2059238130 @default.
- W1978177588 cites W2060987592 @default.
- W1978177588 cites W2064814296 @default.
- W1978177588 cites W2068434955 @default.
- W1978177588 cites W2068780626 @default.
- W1978177588 cites W2086247286 @default.
- W1978177588 cites W2086812063 @default.
- W1978177588 cites W2092998879 @default.
- W1978177588 cites W2095340425 @default.
- W1978177588 cites W2105869727 @default.
- W1978177588 cites W2112093932 @default.
- W1978177588 cites W2153865947 @default.
- W1978177588 cites W2950355852 @default.
- W1978177588 cites W2951762533 @default.
- W1978177588 cites W2952263163 @default.
- W1978177588 doi "https://doi.org/10.1021/jp048601q" @default.
- W1978177588 hasPublicationYear "2004" @default.
- W1978177588 type Work @default.
- W1978177588 sameAs 1978177588 @default.
- W1978177588 citedByCount "24" @default.
- W1978177588 countsByYear W19781775882012 @default.
- W1978177588 countsByYear W19781775882014 @default.
- W1978177588 countsByYear W19781775882015 @default.
- W1978177588 countsByYear W19781775882016 @default.
- W1978177588 countsByYear W19781775882019 @default.
- W1978177588 crossrefType "journal-article" @default.
- W1978177588 hasAuthorship W1978177588A5016349284 @default.
- W1978177588 hasAuthorship W1978177588A5041404847 @default.
- W1978177588 hasConcept C112887158 @default.
- W1978177588 hasConcept C147597530 @default.
- W1978177588 hasConcept C147789679 @default.
- W1978177588 hasConcept C15744967 @default.
- W1978177588 hasConcept C178790620 @default.
- W1978177588 hasConcept C185592680 @default.
- W1978177588 hasConcept C2776029896 @default.
- W1978177588 hasConcept C2779400197 @default.
- W1978177588 hasConcept C2780471494 @default.
- W1978177588 hasConcept C32909587 @default.
- W1978177588 hasConcept C77805123 @default.
- W1978177588 hasConceptScore W1978177588C112887158 @default.
- W1978177588 hasConceptScore W1978177588C147597530 @default.
- W1978177588 hasConceptScore W1978177588C147789679 @default.
- W1978177588 hasConceptScore W1978177588C15744967 @default.
- W1978177588 hasConceptScore W1978177588C178790620 @default.
- W1978177588 hasConceptScore W1978177588C185592680 @default.
- W1978177588 hasConceptScore W1978177588C2776029896 @default.
- W1978177588 hasConceptScore W1978177588C2779400197 @default.
- W1978177588 hasConceptScore W1978177588C2780471494 @default.
- W1978177588 hasConceptScore W1978177588C32909587 @default.
- W1978177588 hasConceptScore W1978177588C77805123 @default.
- W1978177588 hasIssue "29" @default.
- W1978177588 hasLocation W19781775881 @default.
- W1978177588 hasOpenAccess W1978177588 @default.
- W1978177588 hasPrimaryLocation W19781775881 @default.
- W1978177588 hasRelatedWork W1184215157 @default.
- W1978177588 hasRelatedWork W2001592714 @default.
- W1978177588 hasRelatedWork W2064719927 @default.
- W1978177588 hasRelatedWork W2094845662 @default.
- W1978177588 hasRelatedWork W2389442934 @default.
- W1978177588 hasRelatedWork W2953193717 @default.
- W1978177588 hasRelatedWork W3186501602 @default.
- W1978177588 hasRelatedWork W4309592405 @default.
- W1978177588 hasRelatedWork W4386854841 @default.
- W1978177588 hasRelatedWork W2743378620 @default.
- W1978177588 hasVolume "108" @default.
- W1978177588 isParatext "false" @default.
- W1978177588 isRetracted "false" @default.
- W1978177588 magId "1978177588" @default.
- W1978177588 workType "article" @default.