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• W1978193634 abstract "The reaction of di(n-propyl)cyclopropenone (7), di(n-butyl)cyclopropenone (16), and bicyclo[12.1.0]pentadeca-1(14)-en-7-yn-15-one (21) with CpCo(CO)2 and CpCo(cod) yielded CpCo-complexed benzoquinone and cyclopentadienone derivatives. When 16 was reacted with CpCo(CO)2 and a 10-fold surplus of 4-octyne, a mixture of CpCo-capped benzoquinone 25 and cyclopentadienone 26 was isolated. The reaction of cyclopropenone 16 containing a 13C-labeled CO group with CpCo(CO)2 yielded a CpCo-capped tetrakis(n-butyl)-p-benzoquinone with one 13C nucleus per molecule as the main product. The mechanism of the formation of p-benzoquinone is discussed on the basis of the results of trapping and labeling experiments." @default.
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• W1978193634 date "2008-03-01" @default.
• W1978193634 modified "2023-09-30" @default.
• W1978193634 title "CpCo-Mediated Reactions of Cyclopropenones: Access to CpCo-Capped Benzoquinone Complexes" @default.
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• W1978193634 doi "https://doi.org/10.1021/om701115w" @default.
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