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- W1978202395 abstract "Water vapour sorption isotherms on sodium and magnesium vermiculite of high charge density were measured at 25 and 50°C. Heats of immersion at various stages of hydration were measured at 25°C. According to X-ray observations during the sorption process, two discrete interlayer hydrates are obtained with one and two monolayers of water between the unit layers of the crystallites. The derived integral entropy of adsorption indicates a reduced freedom of motion of the interlayer water molecules compared with that for water molecules in the liquid state. Comparison of the apparent density of the hydrated clay with the calculated crystallographic density indicates that interlayer water is slightly more densily packed than liquid water. However, the bulk density of water in a sodium vermiculite suspension is normal for the water in excess of the two hydration layers." @default.
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- W1978202395 date "1970-01-01" @default.
- W1978202395 modified "2023-09-23" @default.
- W1978202395 title "Interlayer water in vermiculite: thermodynamic properties, packing density, nuclear pulse resonance, and infra-red absorption" @default.
- W1978202395 doi "https://doi.org/10.1039/sd9700100187" @default.
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