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- W1978203496 abstract "The photochemical reactions of (p-benzoylphenyl)diphenylmethyl (1) and (p-benzoylphenyl)bis(4-tert-butylphenyl)methyl (2) in various solvents were investigated. The photophysical parameters of the first excited doublet state of the radicals were measured using spectroscopic and kinetic methods and led to a “molecular rotor” model to characterize the excited-state behavior. The charge-transfer excited state for both radicals was observed. Photoproducts separated from the photolysis of 1 and 2 in benzene suggest photodecomposition proceeds via H-abstraction (55%), fragmentation (20%), cyclization (10%), and addition (10%)." @default.
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- W1978203496 date "2000-05-02" @default.
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- W1978203496 title "Photochemistry and Photophysics of (<i>p</i>-Benzoylphenyl)diphenylmethyl and (<i>p</i>-Benzoylphenyl)bis(4-<i>tert</i>-butylphenyl)methyl Radicals in Different Solvents" @default.
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- W1978203496 doi "https://doi.org/10.1021/jp000227g" @default.
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