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- W1978214195 abstract "The reaction of p-nitrophenyl benzenesulfonates has been investigated in dioxane-water solvent. The overall rate constant, kA, was separated into two composite rate constants, kAr, and kSO2, corresponding to the cleavage of C–O and S–O bonds respectively. The reactivities of hydroxide and thiophenoxide in this reaction were compared. The overall rate constant was found to be several times larger with OH− than with PhS−. The reactivity of OH− was largely due to its higher reactivity toward sulfur, while its reactivity toward carbon atom was comparable to that of PhS−. Substituent effect of the nucleophile, thiophenoxide and of the substrate shed some light on the mechanism of this reaction." @default.
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- W1978214195 date "1969-10-01" @default.
- W1978214195 modified "2023-09-26" @default.
- W1978214195 title "Reaction of<i>p</i>-Nitrophenyl Benzenesulfonates with Thiophenoxides" @default.
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- W1978214195 doi "https://doi.org/10.1246/bcsj.42.2894" @default.
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