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• W1978214331 abstract "Two pyridinecarboxamide cobalt dicyanide building blocks and Mn(III) compounds have been employed to assemble cyanide-bridged heterometallic complexes, resulting in three trinuclear cyanide-bridged <TEX>$Co^{III}-Mn^{II}$</TEX> complexes: <TEX>${[Mn(MeOH)_4][Co(bpb)(CN)_2]_2}{cdot}2MeOH{cdot}2H_2O$</TEX> (1), <TEX>${[Mn(MeOH)_4][Co(bpmb)(CN)_2]_2}{cdot}2MeOH{cdot}2H_2O$</TEX> (2) and <TEX>${[Mn(DMF)_2(en)_2][Co(bpb)(CN)_2]_2}{cdot}2DMF{cdot}H_2O$</TEX> (3) (<TEX>$bpb^{2-}$</TEX> = 1,2-bis(pyridine-2-carboxamido)benzenate, <TEX>$bpmb^{2-}$</TEX> = 1,2-bis(pyridine-2-carboxamido)-4-methyl-benzenate, en = ethylenediamine). Single crystal X-ray diffraction analysis shows their similar sandwich-like structures, in which the two cyanide-containing building blocks act as monodentate ligands through one of their two cyanide groups to coordinate the Mn(II) center. For complex 3, it was further linked into one-dimensional structure by ethylenediamine acting as bridges. Investigation of the magnetic properties of complex 3 reveals weak antiferromagnetic coupling between the neighboring Mn(II) centers through the bridging ethylenediamine molecule. A best-fit to the magnetic susceptibilities of complex 3 gave the magnetic coupling constant J = -0.073(2) <TEX>$cm^{-1}$</TEX>." @default.
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• W1978214331 date "2011-08-20" @default.
• W1978214331 modified "2023-10-16" @default.
• W1978214331 title "Cyanide-bridged Trinuclear and Ethylenediamine-bridged One-dimensional Cobalt(III)-Manganese(II) Complexes: Synthesis, Crystal Structures and Magnetic Properties" @default.
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• W1978214331 doi "https://doi.org/10.5012/bkcs.2011.32.8.2544" @default.
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