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- W1978216876 abstract "New fluorite related mixed oxides of molybdenum (V and VI) and lanthanides (Ln = La to Tb) with general formula Ln2nMoV2MoVIn−2O6n−1 (n=6) have been characterized in the systems Ln2O31bMoO21bMoO3 for molar ratios LnMo = 21 and oxygen partial pressures ranging from 10−7.10 to 10−10.5 atm. X-ray diffraction patterns of all compounds show very strong f.c.c. type reflections and a few very weak superstructure lines. Single crystal study on the lanthanum compound revealed the unit cell to be orthorhombic (space group Pcmn or Pc21n), allowed satisfactory indexation of all weak lines and confirmed the formula Ln6Mo12O35 proposed. Possible structural relationship to binary or ternary rare earth oxides of the series MnO2n−2 is discussed." @default.
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- W1978216876 date "1978-09-01" @default.
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- W1978216876 title "Synthesis and characterization of fluorite related molybdates Ln12Mo6O35" @default.
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- W1978216876 doi "https://doi.org/10.1016/0025-5408(78)90106-x" @default.
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