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• W1978224727 abstract "The cohesive energy of layered ionic compounds consists of contributions of the Madelung energy, favouring symmetric coordinations, a repulsive energy, and a polarization energy stabilizing an asymmetric coordination of the polarizable anions. This explains the occurrence of layer-type structures for compounds with highly polarizable anions and small cations. The anisotropy of the dielectric constant and of the optical lattice vibrations of layered compounds is discussed in terms of a simple model with polarizable ions. The observed anisotropies are attributed to the presence of large static dipoles at the anions. Many layered materials show lattice distortions at low temperatures. The different types of distortions, such as charge density waves, metal clustering due to metal-metal bonding, and ferroelectric distortions, are discussed." @default.
• W1978224727 created "2016-06-24" @default.
• W1978224727 creator A5091833038 @default.
• W1978224727 date "1981-05-01" @default.
• W1978224727 modified "2023-09-25" @default.
• W1978224727 title "Anisotropy of lattice vibrations of layered compounds" @default.
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• W1978224727 doi "https://doi.org/10.1016/0378-4363(81)90265-5" @default.
• W1978224727 hasPublicationYear "1981" @default.
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