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- W1978239898 abstract "Double-decker phthalocyanine complexes with Tb3+ or Dy3+ showed slow magnetization relaxation as a single-molecular property. The temperature ranges in which the behavior was observed were far higher than that of the transition-metal-cluster single-molecule magnets (SMMs). The significant temperature rise results from a mechanism in the relaxation process different from that in the transition-metal-cluster SMMs. The effective energy barrier for reversal of the magnetic moment is determined by the ligand field around a lanthanide ion, which gives the lowest degenerate substate a large |Jz| value and large energy separations from the rest of the substates in the ground-state multiplets." @default.
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- W1978239898 date "2003-06-25" @default.
- W1978239898 modified "2023-10-10" @default.
- W1978239898 title "Lanthanide Double-Decker Complexes Functioning as Magnets at the Single-Molecular Level" @default.
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- W1978239898 doi "https://doi.org/10.1021/ja029629n" @default.
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