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- W1978248862 abstract "The fluorescence excitation and dispersed fluorescence spectra of a mixed dimer of p-difluorobenzene (pdf) and p-xylene h10 (px) or p-xylene d10 (pxd) formed in a supersonic expansion have been studied in the spectral region of the monomers origins. The excitation spectrum of pdf–px dimer exhibits two kinds of features, one being red shifted from px000 and the other blue shifted from pdf 000 . Deuteration of the px moiety does not modify the observed shifts of the heterodimer absorptions with respect to each monomer 000 transition, and allows assignment of each absorption to the localized excitation of either the px or the pdf half of the complex. Dispersed fluorescence resulting from the excitation of the p-xylene moiety in the complex (pdf–px* or pdf–pxd*) exhibits two components which may indicate a geometry change in the pdf–px* (or pdf–pxd*) excited complex. Dispersed fluorescence resulting from the excitation of the p-difluorobenzene half of the pdf–px complex (pdf*–px) is similar to that of pdf–px* excited state, i.e., displays the characteristics of p-xylene 00 fluorescence. The pdf*–pxd excited complex fluorescence shows the superposition of the resonance fluorescence from the initially excited level (which is characteristic of the p-difluorobenzene 00 fluorescence) together with the pdf–pxd* emission. These results give evidence that electronic excitation has been transfered within the excited complex from the pdf moiety to the px (pxd) moiety." @default.
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- W1978248862 title "Electronic excitation transfer in a mixed dimer of <i>p</i>‐xylene and <i>p</i>‐difluorobenzene" @default.
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- W1978248862 doi "https://doi.org/10.1063/1.457774" @default.
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