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• W1978257076 endingPage "1891" @default.
• W1978257076 startingPage "1882" @default.
• W1978257076 abstract "Three binuclear AgI complexes based on β-diketonate and N-donor ligands, [Ag2(2,3-bpp)2(btfa)2] (1) and [Ag2(2,3-bpp)2(cbtfa)2] (2), and [Ag2(2,3-bpp)2(mbtfa)2] (3), where 2,3-bpp is 2,3-bis(2-pyridyl)pyrazine, Hbtfa is benzoyltrifluoroacetone, Hcbtfa is 4-chlorobenzoyltrifluoroacetone, and Hmbtfa is 4-methoxybenzoyltrifluoroacetone, were prepared and characterized by elemental analysis, IR, and 1H NMR spectroscopy and X-ray crystallography. Thermal and electrochemical properties were also studied. The complexes are structurally quite similar. Three nitrogen atoms of 2,3-bpp in 1, 2, and 3 are donors toward two silver(I) ions in syn-conformation. Abundant weak interactions, such as π···π, C–H···F, and C–H···O interactions, provide additional assembly forces, leading to 3-D supramolecular networks for 1–3." @default.
• W1978257076 created "2016-06-24" @default.
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• W1978257076 date "2012-05-09" @default.
• W1978257076 modified "2023-10-06" @default.
• W1978257076 title "Assembly of three binuclear complexes of Ag^Iwith 2,3-bis(2-pyridyl)pyrazine and benzoyltrifluoroacetonate ligands" @default.
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• W1978257076 doi "https://doi.org/10.1080/00958972.2012.683867" @default.
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