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- W1978260037 abstract "In the framework of ab initio pseudopotential calculations, a method is presented to compute an effective spin-orbit Hamiltonian within a nonorthogonal diabatic representation separating the ionic and covalent subspaces. The resulting Hund's case c adiabatic curves display long range structures. We predict that a small $(ensuremath{approx}1{mathrm{cm}}^{ensuremath{-}1})$ fine-structure splitting of an ionic $^{3}ensuremath{Pi}_{u}$ curve is manifested in the spectrum of the excited N${mathrm{a}}_{2}$ molecule slightly below the $(3p^{2}P_{1/2}+3p^{2}P_{1/2})$ asymptote as a series of well identified quadruplets. They should be observed in two-color photoassociation spectroscopy experiments using cold atoms." @default.
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- W1978260037 date "1996-04-15" @default.
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- W1978260037 title "Long Range Potentials for Two<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>Na</mml:mi><mml:mo>(</mml:mo><mml:mn>3</mml:mn><mml:mi mathvariant=italic>p</mml:mi><mml:mo>)</mml:mo></mml:math>Atoms Including Ionic-Covalent Interaction and Fine Structure: Application to Two-Color Photoassociation Spectroscopy" @default.
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- W1978260037 doi "https://doi.org/10.1103/physrevlett.76.2858" @default.
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