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- W1978260609 startingPage "2347" @default.
- W1978260609 abstract "Reaction mechanisms between methyl methylthiomethyl sulfoxide (MTMSO) and hydrated electron (eaq−) or hydroxyl radical (OH· radical) have been studied in aqueous solutions with various pH values by means of pulse radiolysis technique. The acid and basic components of equilibrium(Remark: Graphics omitted.)and(Remark: Graphics omitted.)are formed for the reaction of eaq−+CH3SCH2SOCH3 and OH· +CH3SCH2SOCH3, respectively. The pKa values of the respective equilibrium are 10 and 9. The anion (I) and (II) have absorption maxima at 375 nm and 360 nm, respectively. The sulfinic acid CH3SCH2SO2− is also formed in the reaction of CH3SCH2SOCH3+OH·. The rate constants have been determined to be k(eaq−+MTMSO)=1.3×108 M−1 s−1 and k(OH· +MTMSO)=3.1×109 M−1 s−1 (1 M=1 mol dm−3). Relative reactivities of OH· radical with thio-methyl bond and sulfinyl group are also discussed." @default.
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- W1978260609 date "1982-08-01" @default.
- W1978260609 modified "2023-09-25" @default.
- W1978260609 title "Pulse Radiolysis Studies on Methyl Methylthiomethyl Sulfoxide in Aqueous Solutions" @default.
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- W1978260609 doi "https://doi.org/10.1246/bcsj.55.2347" @default.
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