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- W1978269370 abstract "Very high-resolution neutron diffraction data have been collected from KD2PO4 (DKPD) at Tc + 5 K. Analysis of these data shows that the P-atom distribution is highly anharmonic, so much so that it can be modelled as disorder over three sites–a central site at the mean position, and two others displaced symmetrically along ±z, where z is the direction that becomes the polar axis of the low-temperature ferroelectric (FE) phase below Tc. The displaced sites correspond to the two FE configurations of the PO4 groups. It is concluded that the population of these sites is ≳ 40% in each, leaving only ≲ 20% at the central site. This indicates a much greater preponderance of the FE configurations just above Tc than predicted by the standard model of phase transitions of this type." @default.
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- W1978269370 date "1990-09-15" @default.
- W1978269370 modified "2023-09-24" @default.
- W1978269370 title "Possible Disorder of the P Atom in KD 2 PO 4" @default.
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- W1978269370 doi "https://doi.org/10.1209/0295-5075/13/2/008" @default.
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