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• W1978290419 endingPage "1451" @default.
• W1978290419 startingPage "1449" @default.
• W1978290419 abstract "In matrix-assisted laser desorption/ionization (MALDI), the true molecular structures of some analytes are not represented by the observed ions due to a redox reaction. In earlier reports, electron transfer from analyte to chemical matrix has been proposed for the oxidation of ferrocene derivatives in MALDI. To address such a redox phenomenon in laser desorption/ionization processes, two ferrocene derivatives, FcCH2CH2Fc and FcCH2NMe2 [Fc:(C5H5)Fe(C5H4)], were analyzed by a matrix-free method, desorption/ionization on porous silicon (DIOS). The oxidized species, Fc+CH2NMe2 and FcCH2CH2Fc+, were detected in the DIOS mass spectra. The results suggested that electron transfer from the analytes to the sample target occurs during the ionization process." @default.
• W1978290419 created "2016-06-24" @default.
• W1978290419 creator A5022419084 @default.
• W1978290419 creator A5044070399 @default.
• W1978290419 creator A5068927152 @default.
• W1978290419 date "2005-12-01" @default.
• W1978290419 modified "2023-10-14" @default.
• W1978290419 title "Oxidation of Ferrocene Derivatives in Desorption/Ionization on Porous Silicon" @default.
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• W1978290419 doi "https://doi.org/10.2116/analsci.21.1449" @default.
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• W1978290419 hasPublicationYear "2005" @default.
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