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- W1978324097 abstract "Abstract Four three‐dimensional heterometallic coordination polymers, [ Ln 2 Cu 4 I 3 (IN) 7 (H 2 O)] n ( 1 , 2 ) and [ Ln Cu 3.5 I 3 (IN) 3.5 (H 2 O) 3 ] n · n H 2 O ( 3 , 4 ) [HIN = isonicotinic acid, Ln = Nd ( 1 ), Gd ( 2 ), La ( 3 ), Eu ( 4 )] were hydrothermally synthesized by using lanthanide oxides, isonicotinic acid, copper chloride, and potassium iodide. The different molar ratio of raw materials results in two distinct types of three‐dimensional frameworks of compounds 1 – 4 . The structure of compounds 1 and 2 are constructed by the layer modules of [ Ln 2 (IN) 7 (H 2 O)] n n– and Cu 4 I 3 clusters, whereas that of compounds 3 and 4 are built by dimeric Ln 2 (IN) 6 (H 2 O) 6 and layered polymeric [Cu 7 I 6 ] n n+ units." @default.
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- W1978324097 date "2010-12-01" @default.
- W1978324097 modified "2023-10-14" @default.
- W1978324097 title "Syntheses and Crystal Structures of LnIII-CuI Coordination Polymers" @default.
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- W1978324097 doi "https://doi.org/10.1002/zaac.201000137" @default.
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