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Matches in SemOpenAlex for { <https://semopenalex.org/work/W1978328601> ?p ?o ?g. }

• W1978328601 endingPage "532" @default.
• W1978328601 startingPage "522" @default.
• W1978328601 abstract "Four members of the electron-transfer series [Fe(NO)(S(2)C(2)R(2))2]z (z = 1+, 0, 1-, 2-) have been isolated as solid materials (R = p-tolyl): [1a](BF4), [1a]0, [Co(Cp)2][1a], and [Co(Cp)2]2[1a]. In addition, complexes [2a]0 (R = 4,4-diphenyl), [3a]0 (R = p-methoxyphenyl), [Et(4)N][4a] (R = phenyl), and [PPh(4)][5a] (R = -CN) have been synthesized and the members of each of their electron-transfer series electrochemically generated in CH(2)Cl(2) solution. All species have been characterized electro- and magnetochemically. Their electronic, Mössbauer, and electron paramagnetic resonance spectra as well as their infrared spectra have been recorded in order to elucidate the electronic structure of each member of the electron-transfer series. It is shown that the monocationic, neutral, and monoanionic species possess an {FeNO}6 (S = 0) moiety where the redox chemistry is sulfur ligand-based, (L)2-(L*)1-: [Fe(NO)(L*)2]+ (S = 0), [Fe(NO)(L*)(L)]0 <--> [Fe(NO)(L)(L*)]0 (S = 1/2), [Fe(NO)(L)2]- (S = 0). Further one-electron reduction generates a dianion with an {FeNO}7 (S = 1/2) unit and two fully reduced, diamagnetic dianions L2-: [Fe(NO)(L)2]2- (S = 1/2)." @default.
• W1978328601 created "2016-06-24" @default.
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• W1978328601 date "2006-12-24" @default.
• W1978328601 modified "2023-09-24" @default.
• W1978328601 title "Electronic Structure of Nitric Oxide Adducts of Bis(diaryl-1,2-dithiolene)iron Compounds: Four-Membered Electron-Transfer Series [Fe(NO)(L)₂]<i>^z</i> (<i>z</i> = 1+, 0, 1−, 2−)" @default.
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• W1978328601 doi "https://doi.org/10.1021/ic061874a" @default.
• W1978328601 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17279832" @default.
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