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- W1978330348 abstract "Techniques have been developed for the synthesis of complexes of the type [Cr3O(O2CR)6(L)3]+ where Rphenyl or tolyl and LH2O or py in non-aqueous solvents. Additionally, the synthesis of an unsymmetric trinuclear complex, [Cr3O(O2CPh)6(OH)(py)2], is reported. These complexes have been characterized by a number of spectroscopic and magnetic techniques including X-ray crystallography, electronic and infrared spectrophotometry, NMR and EPR spectroscopy, mass spectrometry, and solution and solid state susceptibility measurements. [Cr3O(O2CPh)6(py)3]ClO4 crystallizes in the hexagonal space group P6, which has a 13.387(4), c 19.186(6) Å and Z2. The structure was refined to give R7.6 and Rw10.1." @default.
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- W1978330348 date "1994-03-01" @default.
- W1978330348 modified "2023-10-10" @default.
- W1978330348 title "Synthesis and characterization of symmetric and unsymmetric oxo-bridged trinuclear chromium benzoate complexes: Crystal and molecular structure of [Cr3O(O2CPh)6(py)3]ClO4" @default.
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- W1978330348 doi "https://doi.org/10.1016/0020-1693(93)03766-4" @default.
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