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- W1978334062 abstract "Cyclic mixed acetals with pendant diazoketone side chains undergo rearrangement to ether-bridged cycloheptane ring systems on treatment with Cu(hfacac)2. Stevens [1,2]-shift of an oxonium ylide furnishes the major product (7), in some cases accompanied by minor amounts of a product (8) resulting from [1,2]-shift of a sulfonium ylide. In the subsequent sulfur-triggered cleavage of the bridging ether, the desired bicyclo[5.3.0]heptene was obtained, along with the product of novel SN2‘ attack on the resulting allylic ketal." @default.
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- W1978334062 date "2005-04-01" @default.
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- W1978334062 title "Hydrazulene Ring Systems via Heteroatom-Assisted [1,2]-Shift of Oxonium and Sulfonium Ylides" @default.
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- W1978334062 doi "https://doi.org/10.1021/ol050396p" @default.
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