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• W1978339931 abstract "This paper introduces a simple, fast and reliable electroanalytical method for differential-pulse polarography based on electrochemical reduction at a dropping mercury electrode. The method was validated for the determination of 2-ethylhexyl-4-methoxycinnamate (EHMC) alone and in association with 4-methylbenzylidene camphor (MBC) or 2-hydroxy-4-methoxybenzophenone (BENZ-3) in samples of commercial cosmetic preparations. The supporting electrolyte that provided the best-defined and most intense peak current for EHMC determination was Britton-Robinson buffer (pH 4.0) in the presence of a cationic surfactant. Under optimized conditions, EHMC exhibited one single peak of reduction at -1.49 V versus Ag/AgCl. A limit of detection of 3.76 x 10(-8)mol L(-1) and a limit of quantitation of 1.25 x 10(-7) mol L(-1) were found for the pure EHMC standard. A good average recovery rate was reached for all the samples analyzed." @default.
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• W1978339931 date "2006-01-15" @default.
• W1978339931 modified "2023-09-23" @default.
• W1978339931 title "Polarographic determination of sunscreen agents in cosmetic products in micellar media" @default.
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• W1978339931 doi "https://doi.org/10.1016/j.talanta.2005.05.007" @default.
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