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- W1978340941 abstract "Tetra-n-butylammonium salts of nickel-bis(2-ferrocenyl-1,4-dithiin-5,6-dithiolate)(1; TBA[Ni(fcvdt)2])and nickel-bis(2,3-diferrocenyl-1,4-dithiin-5,6-dithiolate)(2; TBA[Ni(dfcvdt)2])have been successfully synthesized. The crystal structures of complex 1 and 2were determined by X-ray analysis. The [Ni(fcvdt)2]−anion has a chair-like conformation with the two ferrocenyl groups foldingup and down while the [Ni(dfcvdt)2]−anion has a boat-like conformation with four ferrocenyl groups foldingup. Cyclic voltammograms of these complexes show two reversible redox peaksat around −0.9 V and −0.2 V (Ag/Ag+,THF) associated with the Ni(II) dithiolate complexand one quasi-reversible peak associated with the ferrocenyl moieties.The complexes exhibit a strong near-IR absorption at 1178 nm (log e = 3.99)for complex 1 and at 1155 nm (log e = 4.06)for complex 2. This suggests thepossibility of utilizing these complexes as near-IR dyes for absorbinglower energy." @default.
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- W1978340941 date "2000-01-01" @default.
- W1978340941 modified "2023-09-23" @default.
- W1978340941 title "Syntheses, X-ray crystal structures and properties of di- and tetra-ferrocenyl nickel-bis(1,4-dithiin-5,6-dithiolate) complexes" @default.
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- W1978340941 doi "https://doi.org/10.1039/b001829p" @default.
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