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- W1978341937 abstract "Abstract The α-ketoacyl complexes trans-M(PPh3)2(Cl)(COCO2R) (M = Pd, R = (CH2)nCHCH2, n = 2, 3, 4, R = (CH2)2CCMe; M = Pt, R = (CH2)nCHCH2, n = 2, 3, 4, R = (CH2)2CCMe) were prepared by treating M(PPh3)4 with ROCOCOCl. Attempts to insert the pendant olefin or acetylene into the α-ketoacyl-to-metal bond through heating failed, since CO deinsertion to form corresponding acyl complexes was predominant. Reaction of [trans-Pt(PPh3)2(NCMe)(COCOR)]BF4 (R = Me, Ph) with norbornylene resulted in the deinsertion of CO from the α-ketoacyl ligand and the formation of [cis-Pt(PPh3)2(C7H10COR)]BF4, an insertion of norbornylene into the corresponding acyl ligand." @default.
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- W1978341937 date "1989-12-01" @default.
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- W1978341937 title "Reactivity of platinum and palladium α-ketoacyl complexes toward olefins and acetylenes" @default.
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- W1978341937 doi "https://doi.org/10.1016/0022-328x(89)85373-2" @default.
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