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- W1978356004 abstract "When a vinylchloride+perfluoralkane system is cooled from room temperature to 77 K, part of the vinylchloride (approximately 4·5 wt.%) dissolves in the glassy perfluoralkane matrix. When γ-irradiated vinylchloride+perfluoralkane specimens are heated, the principal process involving polymerization of the monomer is observed in the softening range at Tg, approximately 180 K. As a result of the process, formation of PVC occurs, the macromolecules of which contain fragments of the perfluoralkane matrix (there are 0·7 -CF2- fragments to each molecule of the monomer C2H3Cl). It is also possible that the formation of a small quantity of PVC occurs during γ-irradiation of the monomer at 77 K." @default.
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- W1978356004 date "1983-01-01" @default.
- W1978356004 modified "2023-09-25" @default.
- W1978356004 title "Radiation polymerization of vinylchloride in a perfluoralkane glassy matrix" @default.
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- W1978356004 doi "https://doi.org/10.1016/0032-3950(83)90313-1" @default.
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